How does an ordinary LED/lcd module work?

Before you can understand OLEDs, it helps if you understand how a conventional LED/lcd module works. Take two slabs of semiconductor material (something like silicon or germanium), one slightly rich in electrons (called n-type) and one slightly poor in electrons (if you prefer, that's the same as saying it's rich in "holes" where electrons should be, which is called p-type). Join the n-type and p-type slabs together and, where they meet, you get a kind of neutral, no-man's land forming at the junction where surplus electrons and holes cross over and cancel one another out. Now connect electrical contacts to the two slabs and switch on the power. If you wire the contacts one way, electrons flow across the junction from the rich side to the poor, while holes flow the other way, and a current flows across the junction and through your circuit.